http://www.nytimes.com/2011/03/18/world/asia/18spent.html?pagewanted=2&_r=1&ref=world
A great article – what the NY Times can be when it wants to…
Details it brings out (or things correcting misunderstandings on my part)
What is a nuclear fuel rod assembly?
Imagine those round dog treats that are shaped like an oatmeal box. Now take a 13 foot long metal straw and fill it up with a string of pellets, made of about 4% Uranium 235 fuel and 96% inert Uranium 238. A brand new fuel rod emits minimal radiation and you could hold it in your hand for days without any radiation consequences to you.
Now take 64 of those rods and put them into a frame, so each rod is held firmly in place and can be easily lifted in and out of the reactor core. The storage tank at reactor #4 is essentially full – it has 1,479 of these fuel assemblies in storage.
A storage tank is like a 39 foot deep swimming pool. The 13 foot high fuel rod assemblies sit on the bottom, covered by another 26 feet of water. The water is light water and laced with boron. It is kept cool by circulating water (that’s what is broken now). That keeps things quiet and the 26 feet of water protects the workers from radiation when they need to go inside the reactor containment building. Under normal circumstances, used fuel rods will cool down enough in 3 to 5 years that they need less cooling. Storage pool #7 at Fukushima is holding the cooled down stored spent fuel.
Fukushima has so much spent fuel in its pools (as does America) because we have failed to develop a way to reprocess the fuel rods or build permanent storage sites (See: Yucca mountain) to get the spent fuel away from the the plants.
Since 1982, US power companies have been paying about $500 million a year into a Nuclear Waste Fund to pay the costs for eventual permanent storage, but like all “trust” funds, it is being used instead to hand out free cheese to poor people and Harry Reed has shut down any idea of using Yucca Mountain. Even if the DOE had the money, the fee being charged is nowhere near the anticipated actual disposal costs. The US military also contributes – as of 2007, the “Trust fund” had $21.7 billion, which is sitting in an “account” over at the U.S. Treasury, the same as the Social Security Trust Fund.
When you take a fuel rod and put it inside a reactor where Nuclear Fission is happening, the neutrons hit the Uranium 235 and that creates more neutrons and heat. The neutrons also hit the inert U238 and suddenly it is no longer inert. It converts eventually into Plutonium 239 which is very radioactive for a very long time, but is also a good nuclear fuel as well, like U235. Other radioactive stuff is also generated – Iodine, Cesium, and Strontium. As long as the fission has stopped, no new radiative byproducts are created (although what you created already continues to decay into other “stuff”). Iodine loses its radiation in a few weeks, but the others stay radioactive for many many years.
As the U235 gets “used up” (down to 1%), the rod is less and less able to keep the fission reaction going, and eventually has to be pulled out of the reactor. At that point, a little over 1% of the fuel rod is Plutonium, which merrily likes to keep emitting neutrons even after the chain reaction has stopped (“Fissile”)
One of the ways to lose water in a storage tank is sloshing during a large earthquake. Another is that a hole is created in the tank and it starts to leak out. Another is that cooling is lost and the water starts to boil off.
Once you lose 26 feet of water, the fuel rods become exposed. The fact that much of what was in Pool #4 was just put there while the plant is shut down means there is more really hot fuel in there than you might want. Without water, the uranium and plutonium keeps generating heat that has nowhere to go. That nice outer metal rod now catches on fire – the things that are gaseous inside the rod escape into the air (Cesium is the marker for loss of the integrity of the fuel rod). Now you have a 13 foot tall stack of white hot pellets. One source in the NY Times story holds out hope the fuel pellets will continue to stand up in a straight 13 foot high stack.
More likely, as the water level keeps dropping the fuel pellets melt and find their way to the bottom of the tank, greatly speeding up the boiling of the water. Once all the water is gone, after a while, you just have a molten mess of spent fuel at the bottom with no neutron absorbers (ie Boron). The 1% of plutonium is a natural neutron emitter, and could cause the chain reaction to resume (re-criticality), generating a huge amount of heat and radiation, but now outside of the radioactive shielding surrounding the reactor core. Instead of a small amount of cooling, the pool of molten stuff would require 100s of thousands of gallons of water per hour to be cooled down, but without containment, you aren’t going to easily stop the neutrons from continuing to gain momentum in the chain reaction.
Information:
U235 has its largest cross section for neutron absorption (measured in barns) for neutrons in the thermal energy range. The cross section (think “likelihood”) for epithermal, fast or slow neutron absorption is almost non-existent by comparison. Pu 239 has very similar cross section characteristics (it is produced from U238 absorption of neutrons). The isotope of Plutonium (Pu) that emits neutrons is Pu240 via spontaneous fission. As fission is the splitting of an atom, it is energetic and the flux of neutrons is highly energetic (this fast, not thermal), there is little to act as a target for those neutrons, so they become an ionization hazard, not a criticality hazard.
Again, heat is the enemy we see here. Endless amounts of decay heat turning structure into sludge. The fuel pellets, being ceramic, lay in a pile (or disintegrate into powder) and keep adding to the heat. Now, lets take the interesting scenario where we introduce massive amounts of cooling water to this pile of sludge and such. Water, as we know, moderates neutrons. This could change the flux distribution radically such that the population of thermal neutrons increases substantially. Now, we have a supercriticality opportunity.
Which is worse? It’s an interesting analysis. Now – we will need Boron and as much as possible.
While reading the NRC document about why the Duke Catawba MOX test failed, I saw that the minimum boron concentration for spent fuel tanks is over 2% (2700 ppm).
The tank on #4 is reported to be about 2,000 tons of water, meaning a minimum of
54054 tons of dissolved Boric acid. If it has a hole in the bottom and is leaking, and they’re just pumping in sea water to dissipate the heat, that explains why they’re gonna use up the entire world’s supply of boric acid pretty fast.Irony is always good. One of the largest US supplies of boric acid can be found where we aren’t being allowed to entomb our spent fuel – Nevada.
For your thinking pleasure…. Boric Acid is a poison
http://www.nlm.nih.gov/medlineplus/ency/article/002485.htm
The lethal dose is somewhere around 5g/Kg of body weight…. so that’s not likely to kill people through inhalation (a 200 pound person would have to inhale or ingest a pound of boric acid)… but long before that, it has health consequences affecting your ability to work, and will start causing kidney damage.
Just one more thing to worry about.